d- and f-Block Elements

General introduction, electronic configuration, occurrence and
characteristics of transition metals, general trends in properties of the first-row transition metals – metallic character, ionization enthalpy, oxidation
states, ionic radii, color, catalytic property, magnetic properties, interstitial
compounds, alloy formation.
Lanthanoids: Electronic configuration, oxidation states, and lanthanoid
contraction and its consequences.

Coordination Compounds

Coordination compounds – Introduction, ligands, coordination number,
color, magnetic properties and shapes, IUPAC nomenclature of
mononuclear coordination compounds. Bonding, Werner’s theory, VBT,
and CFT.

Aldehydes, Ketones and Carboxylic Acids

Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods
of preparation, physical and chemical properties, mechanism of nucleophilic
addition, the reactivity of alpha hydrogen in aldehydes, uses.
Carboxylic Acids: Nomenclature, acidic nature, methods of preparation,
physical and chemical properties; uses.

Amines

Amines: Nomenclature, classification, structure, methods of preparation,
physical and chemical properties, uses, identification of primary, secondary
and tertiary amines.

Surface Chemistry

Adsorption – physisorption and chemisorption, factors affecting adsorption
of gases on solids, colloidal state: the distinction between true solutions,
colloids and suspension; lyophilic, lyophobic, multi-molecular and
macromolecular colloids; properties of colloids; Tyndall effect, Brownian
movement, electrophoresis, coagulation.

Chemical Kinetics

Rate of a reaction (Average and instantaneous), factors affecting rate of
reaction: concentration, temperature, catalyst; order and molecularity of a
reaction, rate law and specific rate constant, integrated rate equations and
half-life (only for zero and first-order reactions).

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